Lithium-ion conducting electrolyte salts for lithium batteries
This paper presents an overview of the various types of lithium salts used to conduct Li+ ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid–electrolyte interface (SEI) formation...
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sg-ntu-dr.10356-1065152021-01-10T10:56:37Z Lithium-ion conducting electrolyte salts for lithium batteries Aravindan, Vanchiappan Gnanaraj, Joe Madhavi, Srinivasan Liu, Hua-Kun School of Materials Science & Engineering Energy Research Institute @ NTU (ERI@N) DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry This paper presents an overview of the various types of lithium salts used to conduct Li+ ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid–electrolyte interface (SEI) formation towards carbonaceous anodes and the effect of anions on the aluminium current collector. The physicochemical and functional parameters relevant to electrochemical properties, that is, electrochemical stabilities, are also presented. The new types of lithium salts, such as the bis(oxalato)borate (LiBOB), oxalyldifluoroborate (LiODFB) and fluoroalkylphosphate (LiFAP), are described in detail with their appropriate synthesis procedures, possible decomposition mechanism for SEI formation and prospect of using them in future generation lithium-ion batteries. Finally, the state-of-the-art of the system is given and some interesting strategies for the future developments are illustrated. 2014-10-01T07:42:13Z 2019-12-06T22:13:20Z 2014-10-01T07:42:13Z 2019-12-06T22:13:20Z 2011 2011 Journal Article Aravindan, V., Gnanaraj, J., Madhavi, S.,& Liu, H. K. (2011). Lithium-ion conducting electrolyte salts for lithium batteries. Chemistry - a European journal, 17(51), 14326-14346. 0947-6539 https://hdl.handle.net/10356/106515 http://hdl.handle.net/10220/23950 10.1002/chem.201101486 162453 en Chemistry - a European journal © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 20 p. |
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DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry Aravindan, Vanchiappan Gnanaraj, Joe Madhavi, Srinivasan Liu, Hua-Kun Lithium-ion conducting electrolyte salts for lithium batteries |
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This paper presents an overview of the various types of lithium salts used to conduct Li+ ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid–electrolyte interface (SEI) formation towards carbonaceous anodes and the effect of anions on the aluminium current collector. The physicochemical and functional parameters relevant to electrochemical properties, that is, electrochemical stabilities, are also presented. The new types of lithium salts, such as the bis(oxalato)borate (LiBOB), oxalyldifluoroborate (LiODFB) and fluoroalkylphosphate (LiFAP), are described in detail with their appropriate synthesis procedures, possible decomposition mechanism for SEI formation and prospect of using them in future generation lithium-ion batteries. Finally, the state-of-the-art of the system is given and some interesting strategies for the future developments are illustrated. |
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School of Materials Science & Engineering |
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School of Materials Science & Engineering Aravindan, Vanchiappan Gnanaraj, Joe Madhavi, Srinivasan Liu, Hua-Kun |
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Article |
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Aravindan, Vanchiappan Gnanaraj, Joe Madhavi, Srinivasan Liu, Hua-Kun |
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Aravindan, Vanchiappan |
title |
Lithium-ion conducting electrolyte salts for lithium batteries |
title_short |
Lithium-ion conducting electrolyte salts for lithium batteries |
title_full |
Lithium-ion conducting electrolyte salts for lithium batteries |
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Lithium-ion conducting electrolyte salts for lithium batteries |
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Lithium-ion conducting electrolyte salts for lithium batteries |
title_sort |
lithium-ion conducting electrolyte salts for lithium batteries |
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2014 |
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https://hdl.handle.net/10356/106515 http://hdl.handle.net/10220/23950 |
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