Reducing mass-transport limitations in cobalt-electrolyte-based dye-sensitized solar cells by photoanode modification
Mass transport has been identified as a limiting problem in the photovoltaic performance of dye-sensitized solar cells based on electrolytes consisting of ionic liquids or cobalt complexes. A mixed TiO2 macroporous–mesoporous morphology employed as photoanode is demonstrated to assist the diffusion...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/106663 http://hdl.handle.net/10220/19625 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | Mass transport has been identified as a limiting problem in the photovoltaic performance of dye-sensitized solar cells based on electrolytes consisting of ionic liquids or cobalt complexes. A mixed TiO2 macroporous–mesoporous morphology employed as photoanode is demonstrated to assist the diffusion of electrolytes with higher viscosity or consisting of bulky redox mediators, such as cobalt di-tert-butyl bipyridine [Co(dtb)3]2+/3+. This morphology with large pores improves the non-linearity of photocurrent response to light intensity indicating better diffusion. The incorporated sub-micrometer pores also reduce recombination and decrease diffusion resistance, as revealed by electrochemical impedance spectroscopy. |
|---|