Graphene liquid marbles as photothermal miniature reactors for reaction kinetics modulation

• Main Authors: Gao, Wei, Lee, Hiang Kwee, Hobley, Jonathan, Liu, Tianxi, Phang, In Yee, Ling, Xing Yi
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Physics
• Online Access: https://hdl.handle.net/10356/106776; http://hdl.handle.net/10220/25089; http://dx.doi.org/10.1002/anie.201412103
• Institution: Nanyang Technological University

We demonstrate the fabrication of graphene liquid marbles as photothermal miniature reactors with precise temperature control for reaction kinetics modulation. Graphene liquid marbles show rapid and highly reproducible photothermal behavior while maintaining their excellent mechanical robustness. By tuning the applied laser power, swift regulation of graphene liquid marble’s surface temperature between 21–135 °C and its encapsulated water temperature between 21–74 °C are demonstrated. The temperature regulation modulates the reaction kinetics in our graphene liquid marble, achieving a 12-fold superior reaction rate constant for methylene blue degradation than at room temperature.