A dicationic iminophosphane

A novel dicationic system containing a PN fragment has been synthesized and structurally characterized. According to the solid-state analysis and theoretical investigation, the dicationic iminophosphane resonance form is the most appropriate description for the dication. However, the contribution fr...

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Bibliographic Details
Main Authors: Ganguly, Rakesh, Loh, Ying Kai, Gurnani, Chitra, Vidović, Dragoslav
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/107403
http://hdl.handle.net/10220/25468
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Institution: Nanyang Technological University
Language: English
Description
Summary:A novel dicationic system containing a PN fragment has been synthesized and structurally characterized. According to the solid-state analysis and theoretical investigation, the dicationic iminophosphane resonance form is the most appropriate description for the dication. However, the contribution from the phosphorus mononitride resonance form is not negligible.