Facile direct insertion of nitrosonium ion (NO+) into a ruthenium-aryl bond

• المؤلفون الرئيسيون: Pat, Pak-Kei, Lau, Tai-Chu, Wong, Chun-Yuen, Chan, Siu-Chung
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Physics
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/107441; http://hdl.handle.net/10220/25490
• المؤسسة: Nanyang Technological University

An insertion reaction of nitrosonium ion (NO+) into the metal−carbon bond of cyclometalated ruthenium(II) complexes is prepared with experimental evidence supporting a bimolecular direct NO+ insertion into the metal−carbon bond (i.e., M−R + NO+ → [M−N(═O)−R]+) but not an intramolecular migratory ins...