Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence

• المؤلفون الرئيسيون: Chan, Siu-Chung, England, Jason, Wieghardt, Karl, Wong, Chun-Yuen
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Physics
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/107442; http://hdl.handle.net/10220/25485

The reaction of a benzofuroxan with [Ru([9]aneS3)(dmso)Cl2] ([9]aneS3 = 1,4,7-trithiacyclononane) and [Ru(bpy)2(CH3CN)2]2+ yields the ruthenium complexes [Ru([9]aneS3)(ON^NO)(Cl)]+ (1a–c) and [Ru(bpy)2(ON^NO)]n+ (n = 2: 2a and 2b; n = 1: 2a− and 2b−), respectively, containing neutral or monoanionic...