Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence

• Main Authors: Chan, Siu-Chung, England, Jason, Wieghardt, Karl, Wong, Chun-Yuen
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2015
• 主題: DRNTU::Science::Physics
• 在線閱讀: https://hdl.handle.net/10356/107442; http://hdl.handle.net/10220/25485
• 機構: Nanyang Technological University

The reaction of a benzofuroxan with [Ru([9]aneS3)(dmso)Cl2] ([9]aneS3 = 1,4,7-trithiacyclononane) and [Ru(bpy)2(CH3CN)2]2+ yields the ruthenium complexes [Ru([9]aneS3)(ON^NO)(Cl)]+ (1a–c) and [Ru(bpy)2(ON^NO)]n+ (n = 2: 2a and 2b; n = 1: 2a− and 2b−), respectively, containing neutral or monoanionic...