A bis(germyliumylidene)silver(I) complex dication

• Main Authors: Seow, Celestine, Muhammad Luthfi Bin Ismail, Xi, Hong-Wei, Li, Yongxin, Lim, Kok Hwa, So, Cheuk-Wai
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2020
• 主題: Science::Chemistry; Science::Chemistry::Inorganic chemistry; Hydrocarbons; Ligands
• 在線閱讀: https://hdl.handle.net/10356/136703

The reaction of the 2,6-bis(imino)phenylchlorogermylene [LGeCl] (1, L = C6H3-2,6-(HC=NtBu)2) with silver(I) trifluoromethanesulfonate (AgOTf) in a molar ratio of 2:3 in toluene afforded a mixture of the bis(germylene)silver(I) complex [{L(TfO)Ge}2Ag(OTf)] (2) and AgCl. Compound 2 was then reacted wi...