Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks

Intriguing porous architectures, fascinating physical and chemical properties, and wide application potentials have made metal–organic frameworks (MOFs) a class of highly promising functional materials. The inherent feature of incorporating decorative organic components as building blocks has facili...

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Main Authors: Li, Pei-Zhou, Wang, Xiao-Jun, Zhao,Yanli
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/137621
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1376212023-02-28T19:28:20Z Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks Li, Pei-Zhou Wang, Xiao-Jun Zhao,Yanli School of Physical and Mathematical Sciences Science::Chemistry Metal-organic Frameworks Click Chemistry Intriguing porous architectures, fascinating physical and chemical properties, and wide application potentials have made metal–organic frameworks (MOFs) a class of highly promising functional materials. The inherent feature of incorporating decorative organic components as building blocks has facilitated MOF constructions by ingenious pre-design and post-synthetic modifications of the organic moieties through appropriate reactions. Meanwhile, the click chemistry has become an effective and robust tool in the fabrication and modification of various functional materials. The azide-alkyne 1,3-dipolar cycloaddition is usually conducted in mild conditions using diversely available substrates to generate 1,4-regioisomers of 1,2,3-triazoles as sole products in high yields, which meets the characteristics of the conceptual click chemistry and has been referred as the premier example of a click reaction. In 2007, the azide-alkyne 1,3-dipolar cycloaddition as a representative reaction of the click chemistry was introduced into the field of MOFs. In the past decade, utilizing the azide-alkyne 1,3-dipolar cycloaddition, not only lots of organic ligands have been designed and synthesized for MOF constructions, but also diverse functional groups have been grafted into/onto MOF networks for targeted applications. Although other click reactions, such as Diels-Alder click reaction and thiol-ene click reaction, have also been introduced into the MOF field, more and more successful examples have undoubtedly demonstrated that the azide-alkyne 1,3-dipolar cycloaddition is a highly efficient click reaction in the MOF construction and modification toward purposed applications. Herein, we highlight representative research progresses on MOFs derived from the azide-alkyne 1,3-dipolar cycloaddition along with their attractive applications. Accepted version 2020-04-06T09:41:15Z 2020-04-06T09:41:15Z 2019 Journal Article Li, P.-Z., Wang, X.-J., & Zhao,Y. (2019). Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks. Coordination Chemistry Reviews, 380, 484-518. doi:10.1016/j.ccr.2018.11.006 0010-8545 https://hdl.handle.net/10356/137621 10.1016/j.ccr.2018.11.006 380 484 518 en Coordination Chemistry Reviews © 2019 Elsevier. All rights reserved. This paper was published in Coordination Chemistry Reviews and is made available with permission of Elsevier. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Metal-organic Frameworks
Click Chemistry
spellingShingle Science::Chemistry
Metal-organic Frameworks
Click Chemistry
Li, Pei-Zhou
Wang, Xiao-Jun
Zhao,Yanli
Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
description Intriguing porous architectures, fascinating physical and chemical properties, and wide application potentials have made metal–organic frameworks (MOFs) a class of highly promising functional materials. The inherent feature of incorporating decorative organic components as building blocks has facilitated MOF constructions by ingenious pre-design and post-synthetic modifications of the organic moieties through appropriate reactions. Meanwhile, the click chemistry has become an effective and robust tool in the fabrication and modification of various functional materials. The azide-alkyne 1,3-dipolar cycloaddition is usually conducted in mild conditions using diversely available substrates to generate 1,4-regioisomers of 1,2,3-triazoles as sole products in high yields, which meets the characteristics of the conceptual click chemistry and has been referred as the premier example of a click reaction. In 2007, the azide-alkyne 1,3-dipolar cycloaddition as a representative reaction of the click chemistry was introduced into the field of MOFs. In the past decade, utilizing the azide-alkyne 1,3-dipolar cycloaddition, not only lots of organic ligands have been designed and synthesized for MOF constructions, but also diverse functional groups have been grafted into/onto MOF networks for targeted applications. Although other click reactions, such as Diels-Alder click reaction and thiol-ene click reaction, have also been introduced into the MOF field, more and more successful examples have undoubtedly demonstrated that the azide-alkyne 1,3-dipolar cycloaddition is a highly efficient click reaction in the MOF construction and modification toward purposed applications. Herein, we highlight representative research progresses on MOFs derived from the azide-alkyne 1,3-dipolar cycloaddition along with their attractive applications.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Li, Pei-Zhou
Wang, Xiao-Jun
Zhao,Yanli
format Article
author Li, Pei-Zhou
Wang, Xiao-Jun
Zhao,Yanli
author_sort Li, Pei-Zhou
title Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
title_short Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
title_full Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
title_fullStr Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
title_full_unstemmed Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
title_sort click chemistry as a versatile reaction for construction and modification of metal-organic frameworks
publishDate 2020
url https://hdl.handle.net/10356/137621
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