Pyridine N-oxide catalyzed living radical polymerization of methacrylates via halogen bonding catalysis

The paper reports the generation of a carbon-center radical (R•) from an alkyl iodide (R-I) via a halogen bonding catalysis using pyridine N-oxide (PO) catalysts. The use of this catalysis in organocatalyzed living radical polymerization was systematically studied over a series of substituted POs. A...

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Bibliographic Details
Main Authors: Xu, Haiyan, Wang, Chen-Gang, Lu, Yunpeng, Goto, Atsushi
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/137698
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Institution: Nanyang Technological University
Language: English