Chiral nitroarenes as enantioselective single-electron-transfer oxidants for carbene-catalyzed radical reactions

• المؤلفون الرئيسيون: Wang, Hongling, Wang, Yuhuang, Chen, Xingkuan, Mou, Chengli, Yu, Shuyan, Chai, Huifang, Jin, Zhichao, Chi, Robin Yonggui
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry::Organic chemistry; Enantioselective; Chirality
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/137777

A new class of chiral oxidants is developed. These readily accessible oxidants contain a nitro group for oxidation and a chiral sulfonamide moiety for stereoselectivity control. The chiral information from the oxidants can effectively transfer to the substrates in carbene-catalyzed β-hydroxylation o...