Visible-light photoredox enables ketone carbonyl alkylation for easy access to tertiary alcohols

• المؤلفون الرئيسيون: Vu, Minh Duy, Das, Mrinmoy, Guo, Aoxin, Ang, Zi-En, D̵okić, Miloš, Soo, Han Sen, Liu, Xue-Wei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry::Organic chemistry; Photoredox Catalysis; HAT Catalyst
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/138401

Being a handle for synthesizing quaternary carbon centers and olefins, together with ubiquitous appearance in organic building blocks, makes tertiary alcohols valuable targets in synthesis. However, traditional syntheses of these alcohols have faced several challenges including the employment of fun...