Hierarchical microboxes constructed by SnS nanoplates coated with nitrogen-doped carbon for efficient sodium storage

The design and synthesis of hierarchical microboxes, assembled from SnS nanoplates coated with nitrogen-doped carbon (NC) as an anode material for sodium-ion batteries, is demonstrated. The template-engaged multistep synthesis of the SnS@NC microboxes involves sequential phase transformation, polydo...

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Bibliographic Details
Main Authors: Wang, Sibo, Fang, Yongjin, Wang, Xiao, Lou, David Xiong Wen
Other Authors: School of Chemical and Biomedical Engineering
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/138606
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Institution: Nanyang Technological University
Language: English
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Summary:The design and synthesis of hierarchical microboxes, assembled from SnS nanoplates coated with nitrogen-doped carbon (NC) as an anode material for sodium-ion batteries, is demonstrated. The template-engaged multistep synthesis of the SnS@NC microboxes involves sequential phase transformation, polydopamine coating, and thermal annealing in N2 . The SnS@NC composite with two-dimensional nano-sized subunits rationally integrates several advantages including shortening the diffusion path of electrons/Na+ ions, improving electric conductivity, and alleviating volume variation of the electrode material. As a result, the SnS@NC microboxes show efficient sodium storage performance with high capacity, good cycling stability, and excellent rate capability.