Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials

Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials

The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a new...

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Bibliographic Details
Main Authors: Peng, Yongwu, Zhao, Meiting, Chen, Bo, Zhang, Zhicheng, Huang, Ying, Dai, Fangna, Lai, Zhuangchai, Cui, Xiaoya, Tan, Chaoliang, Zhang, Hua
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2020
Subjects:
Engineering::Materials
Core–shell Structure
Covalent Organic Frameworks
Online Access:https://hdl.handle.net/10356/138715
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Institution: Nanyang Technological University
Language: English
Description
Summary:The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a new type of MOF@COF core-shell hybrid material, i.e., NH2 -MIL-68@TPA-COF, with high crystallinity and hierarchical pore structure, is synthesized. As a proof-of-concept application, the obtained NH2 -MIL-68@TPA-COF hybrid material is used as an effective visible-light-driven photocatalyst for the degradation of rhodamine B. The synthetic strategy in this study opens up a new avenue for the construction of other MOF-COF hybrid materials, which could have various promising applications.

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