Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds

• Main Authors: Li, Jia, Luo, Man, Sheng, Xingchao, Hua, Haiming, Yao, Weiwei, Pullarkat, Sumod Appukuttan, Xu, Li, Ma, Mengtao
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2020
• 主題: Science::Chemistry; β-diketiminate Magnesium; Hydroboration
• 在線閱讀: https://hdl.handle.net/10356/138741

A series of unsymmetrical β-diketimine coordinated magnesium(i) complexes have been successfully synthesized via reductions of related magnesium(ii) halide complexes with a sodium reducing reagent in toluene or n-hexane solution. All the unsymmetrical magnesium(i) complexes prepared have been crysta...