NHC-silyliumylidene cation-catalyzed hydroboration of isocyanates with pinacolborane

NHC-silyliumylidene cation-catalyzed hydroboration of isocyanates with pinacolborane

The low-oxidation-state silicon-catalyzed hydroboration of isocyanates with pinacolborane (HBpin) using the NHC-silyliumylidene cation catalyst [(IMe)2SiH]I (1, IMe = :C{N(Me)C(Me)}2) is described. In the catalysis, the Si lone pair electrons activate isocyanates, and the latter react with HBpin to...

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Bibliographic Details
Main Authors: Teo, Yeow-Chuan, Loh, Dexter, Leong, Bi-Xiang, Zhang, Zheng-Feng, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2024
Subjects:
Chemistry
Formamides
Hydroboration
Online Access:https://hdl.handle.net/10356/173375
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/173375

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