NHC-silyliumylidene cation-catalyzed hydroboration of isocyanates with pinacolborane
The low-oxidation-state silicon-catalyzed hydroboration of isocyanates with pinacolborane (HBpin) using the NHC-silyliumylidene cation catalyst [(IMe)2SiH]I (1, IMe = :C{N(Me)C(Me)}2) is described. In the catalysis, the Si lone pair electrons activate isocyanates, and the latter react with HBpin to...
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Main Authors: | Teo, Yeow-Chuan, Loh, Dexter, Leong, Bi-Xiang, Zhang, Zheng-Feng, Su, Ming-Der, So, Cheuk-Wai |
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Other Authors: | School of Chemistry, Chemical Engineering and Biotechnology |
Format: | Article |
Language: | English |
Published: |
2024
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/173375 |
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Institution: | Nanyang Technological University |
Language: | English |
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