Aluminum-hydride-catalyzed hydroboration of carbon dioxide

Aluminum-hydride-catalyzed hydroboration of carbon dioxide

This study describes the first use of a bis(phosphoranyl)methanido aluminum hydride, [ClC(PPh2NMes)2AlH2] (2, Mes = Me3C6H2), for the catalytic hydroboration of CO2. Complex 2 was synthesized by the reaction of a lithium carbenoid [Li(Cl)C(PPh2NMes)2] with 2 equiv of AlH3·NEtMe2 in toluene at -78 °C...

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Bibliographic Details
Main Authors: Chia, Cher-Chiek, Teo, Yeow-Chuan, Cham, Ning, Ho, Samuel Ying-Fu, Ng, Zhe-Hua, Toh, Hui-Min, Mézailles, Nicolas, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Mixtures
Hydrocarbons
Online Access:https://hdl.handle.net/10356/151886
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/151886

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