Donor-acceptor stabilized tetra(silanimine)

• المؤلفون الرئيسيون: Shan, Yu-Liang, Leong, Bi-Xiang, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Mixtures; Hydrocarbons
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/139458
• المؤسسة: Nanyang Technological University

The synthesis of an oligo(silanimine) is described. The reaction of the amidinato silylene [LSiN(SiMe3)2] (1, L = PhC(NtBu)2) with SiI4 in toluene afforded a mixture of the silanimine [LSi(I)NSiI3] (2), SiMe3I, and Si2I6. The mechanistic studies showed that 1 reacts with SiI4 to form the silyl ionic...