Donor-acceptor stabilized tetra(silanimine)

The synthesis of an oligo(silanimine) is described. The reaction of the amidinato silylene [LSiN(SiMe3)2] (1, L = PhC(NtBu)2) with SiI4 in toluene afforded a mixture of the silanimine [LSi(I)NSiI3] (2), SiMe3I, and Si2I6. The mechanistic studies showed that 1 reacts with SiI4 to form the silyl ionic...

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Bibliographic Details
Main Authors: Shan, Yu-Liang, Leong, Bi-Xiang, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/139458
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Institution: Nanyang Technological University
Language: English