A versatile NHC-parent silyliumylidene cation for catalytic chemo- and regioselective hydroboration

A versatile NHC-parent silyliumylidene cation for catalytic chemo- and regioselective hydroboration

This study describes the first use of a silicon(II) complex, NHC-parent silyliumylidene cation complex [(IMe)2SiH]I (1, IMe = :C{N(Me)C(Me)}2) as a versatile catalyst in organic synthesis. Complex 1 (loading: 10 mol %) was shown to act as an efficient catalyst (reaction time: 0.08 h, yield: 94%, TOF...

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Bibliographic Details
Main Authors: Leong, Bi-Xiang, Lee, Jiawen, Li, Yan, Yang, Ming-Chung, Siu, Chi-Kit, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
N-heterocyclic Silylene
Stable Silylene
Online Access:https://hdl.handle.net/10356/151889
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/151889

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