Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth

Colloidal quantum wells (CQWs) are regarded as a highly promising class of optoelectronic materials, thanks to their unique excitonic characteristics of high extinction coefficients and ultranarrow emission bandwidths. Although the exploration of CQWs in light-emitting diodes (LEDs) is impressive, t...

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Main Authors: Liu, Baiquan, Altintas, Yemliha, Wang, Lin, Shendre, Sushant, Sharma, Manoj, Sun, Handong, Mutlugun, Evren, Demir, Hilmi Volkan
Other Authors: School of Electrical and Electronic Engineering
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/140206
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spelling sg-ntu-dr.10356-1402062023-02-28T19:44:36Z Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth Liu, Baiquan Altintas, Yemliha Wang, Lin Shendre, Sushant Sharma, Manoj Sun, Handong Mutlugun, Evren Demir, Hilmi Volkan School of Electrical and Electronic Engineering School of Physical and Mathematical Sciences Centre of Excellence for Semiconductor Lighting and Displays Engineering::Electrical and electronic engineering Colloidal Quantum Wells Core/shell Structures Colloidal quantum wells (CQWs) are regarded as a highly promising class of optoelectronic materials, thanks to their unique excitonic characteristics of high extinction coefficients and ultranarrow emission bandwidths. Although the exploration of CQWs in light-emitting diodes (LEDs) is impressive, the performance of CQW-LEDs lags far behind other types of soft-material LEDs (e.g., organic LEDs, colloidal-quantum-dot LEDs, and perovskite LEDs). Herein, high-efficiency CQW-LEDs reaching close to the theoretical limit are reported. A key factor for this high performance is the exploitation of hot-injection shell (HIS) growth of CQWs, which enables a near-unity photoluminescence quantum yield (PLQY), reduces nonradiative channels, ensures smooth films, and enhances the stability. Remarkably, the PLQY remains 95% in solution and 87% in film despite rigorous cleaning. Through systematically understanding their shape-, composition-, and device-engineering, the CQW-LEDs using CdSe/Cd0.25 Zn0.75 S core/HIS CQWs exhibit a maximum external quantum efficiency of 19.2%. Additionally, a high luminance of 23 490 cd m-2 , extremely saturated red color with the Commission Internationale de L'Eclairage (CIE) coordinates of (0.715, 0.283), and stable emission are obtained. The findings indicate that HIS-grown CQWs enable high-performance solution-processed LEDs, which may pave the path for future CQW-based display and lighting technologies. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2020-05-27T06:02:46Z 2020-05-27T06:02:46Z 2020 Journal Article Liu, B., Altintas, Y., Wang, L., Shendre, S., Sharma, M., Sun, H., . . . Demir, H. V. (2020). Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth. Advanced Materials, 32(8), 1905824-. doi:10.1002/adma.201905824 0935-9648 https://hdl.handle.net/10356/140206 10.1002/adma.201905824 31867764 2-s2.0-85076889973 8 32 en Advanced Materials This is the accepted version of the following article: Liu, B., Altintas, Y., Wang, L., Shendre, S., Sharma, M., Sun, H., . . . Demir, H. V. (2020). Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth. Advanced materials, 32(8), 1905824-., which has been published in final form at doi:10.1002/adma.201905824. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html]. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering::Electrical and electronic engineering
Colloidal Quantum Wells
Core/shell Structures
spellingShingle Engineering::Electrical and electronic engineering
Colloidal Quantum Wells
Core/shell Structures
Liu, Baiquan
Altintas, Yemliha
Wang, Lin
Shendre, Sushant
Sharma, Manoj
Sun, Handong
Mutlugun, Evren
Demir, Hilmi Volkan
Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
description Colloidal quantum wells (CQWs) are regarded as a highly promising class of optoelectronic materials, thanks to their unique excitonic characteristics of high extinction coefficients and ultranarrow emission bandwidths. Although the exploration of CQWs in light-emitting diodes (LEDs) is impressive, the performance of CQW-LEDs lags far behind other types of soft-material LEDs (e.g., organic LEDs, colloidal-quantum-dot LEDs, and perovskite LEDs). Herein, high-efficiency CQW-LEDs reaching close to the theoretical limit are reported. A key factor for this high performance is the exploitation of hot-injection shell (HIS) growth of CQWs, which enables a near-unity photoluminescence quantum yield (PLQY), reduces nonradiative channels, ensures smooth films, and enhances the stability. Remarkably, the PLQY remains 95% in solution and 87% in film despite rigorous cleaning. Through systematically understanding their shape-, composition-, and device-engineering, the CQW-LEDs using CdSe/Cd0.25 Zn0.75 S core/HIS CQWs exhibit a maximum external quantum efficiency of 19.2%. Additionally, a high luminance of 23 490 cd m-2 , extremely saturated red color with the Commission Internationale de L'Eclairage (CIE) coordinates of (0.715, 0.283), and stable emission are obtained. The findings indicate that HIS-grown CQWs enable high-performance solution-processed LEDs, which may pave the path for future CQW-based display and lighting technologies.
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Liu, Baiquan
Altintas, Yemliha
Wang, Lin
Shendre, Sushant
Sharma, Manoj
Sun, Handong
Mutlugun, Evren
Demir, Hilmi Volkan
format Article
author Liu, Baiquan
Altintas, Yemliha
Wang, Lin
Shendre, Sushant
Sharma, Manoj
Sun, Handong
Mutlugun, Evren
Demir, Hilmi Volkan
author_sort Liu, Baiquan
title Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
title_short Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
title_full Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
title_fullStr Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
title_full_unstemmed Record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
title_sort record high external quantum efficiency of 19.2% achieved in light-emitting diodes of colloidal quantum wells enabled by hot-injection shell growth
publishDate 2020
url https://hdl.handle.net/10356/140206
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