A high-performance SDC-infiltrated nanoporous silver cathode with superior thermal stability for low temperature solid oxide fuel cells

A high-performance SDC-infiltrated nanoporous silver cathode with superior thermal stability for low temperature solid oxide fuel cells

Superior thermal stability of a nanoporous silver thin film cathode is enabled by covering the silver nanoparticles with a thin layer of samarium-doped ceria (SDC). A simple solution infiltration process followed by post heat treatment at 500 °C is applied to coat a thin SDC layer over inkjet-printe...

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Bibliographic Details
Main Authors: Lee, Tsung-Han, Fan, Liangdong, Yu, Chen-Chiang, Wiria, Florencia Edith, Su, Pei-Chen
Other Authors: School of Mechanical and Aerospace Engineering
Format: Article
Language:English
Published: 2020
Subjects:
Engineering::Mechanical engineering
SDC-infiltrated Nanoporous Silver Cathode
Fuel Cells
Online Access:https://hdl.handle.net/10356/140771
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Institution: Nanyang Technological University
Language: English
Description
Summary:Superior thermal stability of a nanoporous silver thin film cathode is enabled by covering the silver nanoparticles with a thin layer of samarium-doped ceria (SDC). A simple solution infiltration process followed by post heat treatment at 500 °C is applied to coat a thin SDC layer over inkjet-printed silver nanoparticle thin films to physically confine the silver nanoparticles to prevent thermal agglomeration. The electrochemical performance of the SDC-infiltrated silver cathode also surpasses that of both a non-infiltrated silver cathode and a typical sputtered nanoporous platinum cathode. A 60 hour fuel cell current stability test using the SDC-infiltrated silver cathode shows only 12.4% current degradation, which is significantly lower than 73.6% degradation from the fuel cell using a non-infiltrated silver cathode.

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