Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries

The rational design of highly-active and stable reversible oxygen electrocatalysts for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) plays a key role in rechargeable metal–air batteries, yet remains a great challenge. Herein, a novel dual-crosslinked hydrogel strat...

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Main Authors: Fu, Gengtao, Liu, Yu, Chen, Yifan, Tang, Yawen, Goodenough, John B., Lee, Jong-Min
Other Authors: School of Chemical and Biomedical Engineering
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/141087
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1410872020-06-04T01:44:27Z Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries Fu, Gengtao Liu, Yu Chen, Yifan Tang, Yawen Goodenough, John B. Lee, Jong-Min School of Chemical and Biomedical Engineering Maritime Institute Engineering::Chemical engineering N-doped Zn–air Batteries The rational design of highly-active and stable reversible oxygen electrocatalysts for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) plays a key role in rechargeable metal–air batteries, yet remains a great challenge. Herein, a novel dual-crosslinked hydrogel strategy is proposed to synthesize a new type of carbon aerogel that anchors the iron–cobalt (FeCo) particles as a bifunctional oxygen catalyst. The proposed hydrogel composed of an organic/inorganic network can be easily obtained by initiating sol–gel polymerization of cyanometalates, chitosan and graphene oxide. After pyrolysis, FeCo nanocrystals can be in situ uniformly immobilized within the N-doped “dual-network” carbon aerogels (FeCo/N-DNC) with a robust 3D porous framework. When used as an electrocatalyst, the newly developed FeCo/N-DNC aerogels exhibit a positive onset potential (0.89 V) and half-wave potential (0.81 V) for the ORR and a low overpotential (0.39 V) at 10 mA cm−2 for the OER, while presenting excellent electrochemical stability after being tested for 10 000 s. More importantly, the FeCo/N-DNC driven Zn–air battery reveals a smaller charge/discharge voltage gap, higher power/energy density and better cycling stability than the costlier Pt/C + RuO2 mixture catalyst. Our findings provide a facile and feasible synthetic strategy for obtaining highly active and stable electrocatalysts. 2020-06-04T01:44:27Z 2020-06-04T01:44:27Z 2018 Journal Article Fu, G., Liu, Y., Chen, Y., Tang, Y., Goodenough, J. B., & Lee, J.-M. (2018). Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries. Nanoscale, 10(42), 19937-19944. doi:10.1039/c8nr05812a 2040-3364 https://hdl.handle.net/10356/141087 10.1039/c8nr05812a 30346015 2-s2.0-85056106387 42 10 19937 19944 en Nanoscale © 2018 The Royal Society of Chemistry. All rights reserved.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic Engineering::Chemical engineering
N-doped
Zn–air Batteries
spellingShingle Engineering::Chemical engineering
N-doped
Zn–air Batteries
Fu, Gengtao
Liu, Yu
Chen, Yifan
Tang, Yawen
Goodenough, John B.
Lee, Jong-Min
Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
description The rational design of highly-active and stable reversible oxygen electrocatalysts for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) plays a key role in rechargeable metal–air batteries, yet remains a great challenge. Herein, a novel dual-crosslinked hydrogel strategy is proposed to synthesize a new type of carbon aerogel that anchors the iron–cobalt (FeCo) particles as a bifunctional oxygen catalyst. The proposed hydrogel composed of an organic/inorganic network can be easily obtained by initiating sol–gel polymerization of cyanometalates, chitosan and graphene oxide. After pyrolysis, FeCo nanocrystals can be in situ uniformly immobilized within the N-doped “dual-network” carbon aerogels (FeCo/N-DNC) with a robust 3D porous framework. When used as an electrocatalyst, the newly developed FeCo/N-DNC aerogels exhibit a positive onset potential (0.89 V) and half-wave potential (0.81 V) for the ORR and a low overpotential (0.39 V) at 10 mA cm−2 for the OER, while presenting excellent electrochemical stability after being tested for 10 000 s. More importantly, the FeCo/N-DNC driven Zn–air battery reveals a smaller charge/discharge voltage gap, higher power/energy density and better cycling stability than the costlier Pt/C + RuO2 mixture catalyst. Our findings provide a facile and feasible synthetic strategy for obtaining highly active and stable electrocatalysts.
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Fu, Gengtao
Liu, Yu
Chen, Yifan
Tang, Yawen
Goodenough, John B.
Lee, Jong-Min
format Article
author Fu, Gengtao
Liu, Yu
Chen, Yifan
Tang, Yawen
Goodenough, John B.
Lee, Jong-Min
author_sort Fu, Gengtao
title Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
title_short Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
title_full Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
title_fullStr Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
title_full_unstemmed Robust N-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable Zn – air batteries
title_sort robust n-doped carbon aerogels strongly coupled with iron – cobalt particles as efficient bifunctional catalysts for rechargeable zn – air batteries
publishDate 2020
url https://hdl.handle.net/10356/141087
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