Unusual Na+ ion intercalation/deintercalation in metal-rich Cu1.8S for Na-ion batteries

A key issue with Na-ion batteries is the development of active materials with stable electrochemical reversibility through the understanding of their sodium storage mechanisms. We report a sodium storage mechanism and properties of a new anode material, digenite Cu1.8S, based on its crystallographic...

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Bibliographic Details
Main Authors: Park, Hyunjung, Kwon, Jiseok, Choi, Heechae, Shin, Donghyeok, Song, Taeseup, Lou, David Xiong Wen
Other Authors: School of Chemical and Biomedical Engineering
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/141451
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Institution: Nanyang Technological University
Language: English
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Summary:A key issue with Na-ion batteries is the development of active materials with stable electrochemical reversibility through the understanding of their sodium storage mechanisms. We report a sodium storage mechanism and properties of a new anode material, digenite Cu1.8S, based on its crystallographic study. It is revealed that copper sulfides (CuxS) can have metal-rich formulas (x ≥ 1.6), due to the unique oxidation state of +1 found in group 11 elements. These phases enable the unit cell to consist of all strong Cu–S bonds and no direct S–S bonds, which are vulnerable to external stress/strain that could result in bond cleavage as well as decomposition. Because of its structural rigidness, the Cu1.8S shows an intercalation/deintercalation reaction mechanism even in a low potential window of 0.1–2.2 V versus Na/Na+ without irreversible phase transformation, which most of the metal sulfides experience through a conversion reaction mechanism. It uptakes, on average, 1.4 Na+ ions per unit cell (∼250 mAh g–1) and exhibits ∼100% retention over 1000 cycles at 2C in a tuned voltage range of 0.5–2.2 V through an overall solid solution reaction with negligible phase separation.