E-H (E = B, Si, C) Bond activation by tuning structural and electronic properties of phosphenium cations

E-H (E = B, Si, C) Bond activation by tuning structural and electronic properties of phosphenium cations

In this work, strategic enhancement of electrophilicity of phosphenium cations for the purpose of small-molecule activation was described. Our synthetic methodology for generation of novel two-coordinate phosphorus(III)-based compounds [{C6H4(MeN)2C}2C·PR]2+ ([2a]2+, R = NiPr2; [2b]2+, R = Ph) was b...

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Bibliographic Details
Main Authors: Đorđević, Nemanja, Ganguly, Rakesh, Petković, Milena, Vidović, Dragoslav
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Hydrogen Abstraction
Anions
Online Access:https://hdl.handle.net/10356/142688
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/142688

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