Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications

Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications

Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic...

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Bibliographic Details
Main Authors: Kayal, Sibnath, Chakraborty, Anutosh, Teo, Benjamin How Wei
Other Authors: School of Mechanical and Aerospace Engineering
Format: Article
Language:English
Published: 2020
Subjects:
Engineering::Mechanical engineering
Aluminium Fumarate MOF
Green Synthesis
Online Access:https://hdl.handle.net/10356/142749
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Institution: Nanyang Technological University
Language: English
Description
Summary:Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications.

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