Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction

• Main Authors: Wo, Xiangyang, Xie, Peizhong, Fu, Weishan, Gao, Cuiqing, Liu, Yanan, Sun, Zuolian, Loh, Teck-Peng
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2020
• Subjects: Engineering::Chemical engineering; Phosphonic Acid Derivative; Phosphites
• Online Access: https://hdl.handle.net/10356/144009
• Institution: Nanyang Technological University

A barium-catalyzed C–OH/P–H dehydrative cross-coupling protocol for the construction of C–P bonds was developed. This reaction was performed in an environmentally benign manner with water as the only by-product. A variety of allylic phosphorus compounds can be isolated in good to excellent yields....