Challenges in cyclometalation : steric effects leading to competing pathways and η1,η2-cyclometalated iridium(iii) complexes

• المؤلفون الرئيسيون: Chen, Jeremy Houguang, Teo, Ronald Hong Xiang, Wong, Jonathan, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Engineering::Chemical engineering; Alkenylation; 8-Aminoquinoline
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/144224

The iridation of (R)-N,N-dimethyl-1-(1-naphthyl)ethylamine in the presence of a base afforded an assortment of products ranging from organic molecules to coordinated systems and cyclometalated complexes. The transformation affirmed the postulation where steric effects within the coordination sphere...