Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)

Barium-doped strontium ferrite oxide is a double perovskite where Ba dopant replaces A-site cation to give better electrochemical performance by means of lattice expansion, and therefore can potentially be a stable fuel electrode for high temperature solid oxide electrolysis cells. Ba0.2Sr1.8Fe1.5Mo...

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Main Authors: Kamlungsua, Kittiwat, Su, Pei-Chen
Other Authors: School of Mechanical and Aerospace Engineering
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/144275
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1442752021-01-28T08:01:31Z Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs) Kamlungsua, Kittiwat Su, Pei-Chen School of Mechanical and Aerospace Engineering Interdisciplinary Graduate School (IGS) Energy Research Institute @ NTU (ERI@N) Science::Chemistry::Physical chemistry::Electrochemistry Solid Oxide Electrolysis Cell Perovskite Barium-doped strontium ferrite oxide is a double perovskite where Ba dopant replaces A-site cation to give better electrochemical performance by means of lattice expansion, and therefore can potentially be a stable fuel electrode for high temperature solid oxide electrolysis cells. Ba0.2Sr1.8Fe1.5Mo0.5O6-δ 28 (B2SFMO) double perovskite as fuel electrode was prepared by solution combustion synthesis with the calcination temperature of 1100 oC. Three-electrode half cell was used to evaluate its electrochemical performance under various steam contents in hydrogen atmosphere both under fuel cell mode and electrolysis mode. Electrochemical impedance spectroscopy demonstrated that hydrogen oxidation reaction involved gaseous adsorption/desorption, oxide transport, and charge transfer processes whereas the oxide transport process in water reduction reaction was split into faster and slower processes at low steam-content region. Polarization study showed the monotonously decreased current density in SOFC mode with the increase in the steam content but it displayed the opposite trend in the current density in SOEC mode with the suitable steam content at 20%. Ministry of Education (MOE) Accepted version The authors acknowledge the financial support from a Tier 1 Grant (M4012132) AcRF Grant No: RG 181/18 funded by the Ministry of Education (MOE). The authors are also grateful to Dr. Liu Qinglin for his kind assistance in the experimental setup. 2020-10-26T07:21:38Z 2020-10-26T07:21:38Z 2020 Journal Article Kamlungsua, K. & Su, P.-C. (2020). Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs). Electrochimica Acta, 355, 136670-136677. doi:10.1016/j.electacta.2020.136670 0013-4686 https://hdl.handle.net/10356/144275 10.1016/j.electacta.2020.136670 355 136670 136677 en Tier 1 Grant (M4012132), AcRF Grant No RG181/18 Electrochimica Acta © 2020 Elsevier Ltd. All rights reserved. This paper was published in Electrochimica Acta and is made available with permission of Elsevier Ltd. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry::Physical chemistry::Electrochemistry
Solid Oxide Electrolysis Cell
Perovskite
spellingShingle Science::Chemistry::Physical chemistry::Electrochemistry
Solid Oxide Electrolysis Cell
Perovskite
Kamlungsua, Kittiwat
Su, Pei-Chen
Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
description Barium-doped strontium ferrite oxide is a double perovskite where Ba dopant replaces A-site cation to give better electrochemical performance by means of lattice expansion, and therefore can potentially be a stable fuel electrode for high temperature solid oxide electrolysis cells. Ba0.2Sr1.8Fe1.5Mo0.5O6-δ 28 (B2SFMO) double perovskite as fuel electrode was prepared by solution combustion synthesis with the calcination temperature of 1100 oC. Three-electrode half cell was used to evaluate its electrochemical performance under various steam contents in hydrogen atmosphere both under fuel cell mode and electrolysis mode. Electrochemical impedance spectroscopy demonstrated that hydrogen oxidation reaction involved gaseous adsorption/desorption, oxide transport, and charge transfer processes whereas the oxide transport process in water reduction reaction was split into faster and slower processes at low steam-content region. Polarization study showed the monotonously decreased current density in SOFC mode with the increase in the steam content but it displayed the opposite trend in the current density in SOEC mode with the suitable steam content at 20%.
author2 School of Mechanical and Aerospace Engineering
author_facet School of Mechanical and Aerospace Engineering
Kamlungsua, Kittiwat
Su, Pei-Chen
format Article
author Kamlungsua, Kittiwat
Su, Pei-Chen
author_sort Kamlungsua, Kittiwat
title Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
title_short Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
title_full Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
title_fullStr Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
title_full_unstemmed Moisture-dependent electrochemical characterization of Ba0.2Sr1.8Fe1.5Mo0.5O6-δ as the fuel electrode for solid oxide electrolysis cells (SOECs)
title_sort moisture-dependent electrochemical characterization of ba0.2sr1.8fe1.5mo0.5o6-δ as the fuel electrode for solid oxide electrolysis cells (soecs)
publishDate 2020
url https://hdl.handle.net/10356/144275
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