Interplay of MLCT and ILCT states in rhenium(I) complexes

• المؤلف الرئيسي: Gordon, Keith
• مؤلفون آخرون: Asian Spectroscopy Conference 2020
• التنسيق: Conference or Workshop Item
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Resonance Raman Spectroscopy; Excited-state Spectroscopy
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/144289

Metal complexes with ligands that have charge-transfer electronic structure can lead to interesting interplay between metal-to-ligand and intra-ligand charge transfer excited states (MLCT and ILCT respectively). In a systematic study of [ReCl(CO)3(dppz-(linker)-TPA)] complexes (Figure 1), we find a...