Photocatalytic activation of inert bonds and their functionalization via hydrogen-evolution cross-couplings
Cross-Coupling reactions are potential tools for construction of complex molecular frameworks of diversified interests via formation of carbon-carbon (C-C) or carbon-heteroatom (C-X) linkage. Compared with conventional transition metal-catalyzed cross-couplings and oxidative crosscouplings, photo...
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
2020
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| Online Access: | https://hdl.handle.net/10356/144411 |
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| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | Cross-Coupling reactions are potential tools for construction of complex molecular frameworks of
diversified interests via formation of carbon-carbon (C-C) or carbon-heteroatom (C-X) linkage.
Compared with conventional transition metal-catalyzed cross-couplings and oxidative crosscouplings,
photocatalytic hydrogen-evolution cross-couplings allow used of less functionalized reagents and proceed without any sacrificial oxidant under mild conditions and by visible-light irradiation. The reactions generally afford the desired cross-coupling products with excellent yields, and hydrogen gas is the only byproduct. In this presentation we will highlight the progress of these reactions in our group. |
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