Diastereoselective intramolecular hydride transfer under brønsted acid catalysis

• المؤلفون الرئيسيون: Wang, Bin, Gandamana, Dhika Aditya, Gagosz, Fabien, Chiba, Shunsuke
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Substituents; Alcohols
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/144900

A diastereoselective hydride transfer process has been developed under Brønsted acid-catalyzed reaction conditions using methyl ethers or acetals as hydride donors and tertiary alcohols or alkenes as precursors of carbocation. The method enables construction of complex molecules having multiple ster...