Main group mechanochemistry : from curiosity to established protocols
In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received...
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sg-ntu-dr.10356-1454292023-02-28T19:26:29Z Main group mechanochemistry : from curiosity to established protocols Tan, Davin García, Felipe School of Physical and Mathematical Sciences Science::Chemistry Mechanochemistry Protocols In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received attention for their ability to enable new reactivity and “unlocking” novel compounds inaccessible by conventional methods. Reflecting the rising popularity of mechanochemistry, many excellent reviews highlighting its benefits have recently been published. Whilst the scope of most of these focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination compounds and supramolecular synthesis, few have addressed the use of mechanochemical ball milling for the synthesis of compounds containing s- and p-block elements. This tutorial review turns the spotlight towards mechanochemical research in the field of inorganic main group chemistry, highlighting significant advantages that solid-state inorganic reactions often possess, and the potential for these to drive the development of greener methodologies within the modern main group arena. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University Published version The authors would like to thank A*STAR AME IRG(A1783c0003), NTU start-up grant (M4080552), and MOE AcRFTier 1 grants (M4011441 and M4011709) for financial support. 2020-12-21T07:53:39Z 2020-12-21T07:53:39Z 2019 Journal Article Tan, D., & García, F. (2019). Main group mechanochemistry : from curiosity to established protocols. Chemical Society Reviews, 48(8), 2274-2292. doi:10.1039/c7cs00813a 0306-0012 https://hdl.handle.net/10356/145429 10.1039/c7cs00813a 8 48 2274 2292 en A1783c0003 M4080552 M4011441 M4011709 Chemical Society Reviews © 2019 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. application/pdf |
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Science::Chemistry Mechanochemistry Protocols Tan, Davin García, Felipe Main group mechanochemistry : from curiosity to established protocols |
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In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received attention for their ability to enable new reactivity and “unlocking” novel compounds inaccessible by conventional methods. Reflecting the rising popularity of mechanochemistry, many excellent reviews highlighting its benefits have recently been published. Whilst the scope of most of these focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination compounds and supramolecular synthesis, few have addressed the use of mechanochemical ball milling for the synthesis of compounds containing s- and p-block elements. This tutorial review turns the spotlight towards mechanochemical research in the field of inorganic main group chemistry, highlighting significant advantages that solid-state inorganic reactions often possess, and the potential for these to drive the development of greener methodologies within the modern main group arena. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Tan, Davin García, Felipe |
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Article |
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Tan, Davin García, Felipe |
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Tan, Davin |
title |
Main group mechanochemistry : from curiosity to established protocols |
title_short |
Main group mechanochemistry : from curiosity to established protocols |
title_full |
Main group mechanochemistry : from curiosity to established protocols |
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Main group mechanochemistry : from curiosity to established protocols |
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Main group mechanochemistry : from curiosity to established protocols |
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main group mechanochemistry : from curiosity to established protocols |
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2020 |
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https://hdl.handle.net/10356/145429 |
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