Main group mechanochemistry : from curiosity to established protocols

In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received...

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Main Authors: Tan, Davin, García, Felipe
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
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Online Access:https://hdl.handle.net/10356/145429
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1454292023-02-28T19:26:29Z Main group mechanochemistry : from curiosity to established protocols Tan, Davin García, Felipe School of Physical and Mathematical Sciences Science::Chemistry Mechanochemistry Protocols In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received attention for their ability to enable new reactivity and “unlocking” novel compounds inaccessible by conventional methods. Reflecting the rising popularity of mechanochemistry, many excellent reviews highlighting its benefits have recently been published. Whilst the scope of most of these focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination compounds and supramolecular synthesis, few have addressed the use of mechanochemical ball milling for the synthesis of compounds containing s- and p-block elements. This tutorial review turns the spotlight towards mechanochemical research in the field of inorganic main group chemistry, highlighting significant advantages that solid-state inorganic reactions often possess, and the potential for these to drive the development of greener methodologies within the modern main group arena. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University Published version The authors would like to thank A*STAR AME IRG(A1783c0003), NTU start-up grant (M4080552), and MOE AcRFTier 1 grants (M4011441 and M4011709) for financial support. 2020-12-21T07:53:39Z 2020-12-21T07:53:39Z 2019 Journal Article Tan, D., & García, F. (2019). Main group mechanochemistry : from curiosity to established protocols. Chemical Society Reviews, 48(8), 2274-2292. doi:10.1039/c7cs00813a 0306-0012 https://hdl.handle.net/10356/145429 10.1039/c7cs00813a 8 48 2274 2292 en A1783c0003 M4080552 M4011441 M4011709 Chemical Society Reviews © 2019 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Mechanochemistry
Protocols
spellingShingle Science::Chemistry
Mechanochemistry
Protocols
Tan, Davin
García, Felipe
Main group mechanochemistry : from curiosity to established protocols
description In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received attention for their ability to enable new reactivity and “unlocking” novel compounds inaccessible by conventional methods. Reflecting the rising popularity of mechanochemistry, many excellent reviews highlighting its benefits have recently been published. Whilst the scope of most of these focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination compounds and supramolecular synthesis, few have addressed the use of mechanochemical ball milling for the synthesis of compounds containing s- and p-block elements. This tutorial review turns the spotlight towards mechanochemical research in the field of inorganic main group chemistry, highlighting significant advantages that solid-state inorganic reactions often possess, and the potential for these to drive the development of greener methodologies within the modern main group arena.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tan, Davin
García, Felipe
format Article
author Tan, Davin
García, Felipe
author_sort Tan, Davin
title Main group mechanochemistry : from curiosity to established protocols
title_short Main group mechanochemistry : from curiosity to established protocols
title_full Main group mechanochemistry : from curiosity to established protocols
title_fullStr Main group mechanochemistry : from curiosity to established protocols
title_full_unstemmed Main group mechanochemistry : from curiosity to established protocols
title_sort main group mechanochemistry : from curiosity to established protocols
publishDate 2020
url https://hdl.handle.net/10356/145429
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