Stereoselective access to highly substituted vinyl ethers via trans-difunctionalization of alkynes with alcohols and iodine(III) electrophile

Stereoselective access to highly substituted vinyl ethers via trans-difunctionalization of alkynes with alcohols and iodine(III) electrophile

A method for the regio- and stereoselective synthesis of highly substituted vinyl ethers via trans-1,2-difunctionalization of alkynes with a cyclic λ3-iodane electrophile (benziodoxole triflate) and alcohols is reported. The reaction tolerates a variety of internal and terminal alkynes as well as va...

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Bibliographic Details
Main Authors: Ding, Wei, Chai, Jinkui, Wang, Chen, Wu, Junliang, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Ethers
Hydrocarbons
Online Access:https://hdl.handle.net/10356/145625
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/145625

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