Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching

A fluoropolyurethane-encapsulated process was designed to rapidly fabricate low-flow resistance surfaces on the zinc substrate. For the further enhancement of the drag-reduction effect, Cu2+-assisted chemical etching was introduced during the fabrication process, and its surface morphology, wettabil...

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Main Authors: Li, Yuanzhe, Cui, Zhe, Zhu, Qiucheng, Narasimalu, Srikanth, Dong, Zhili
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2021
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Online Access:https://hdl.handle.net/10356/146050
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1460502023-07-14T15:53:06Z Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching Li, Yuanzhe Cui, Zhe Zhu, Qiucheng Narasimalu, Srikanth Dong, Zhili School of Materials Science and Engineering Energy Research Institute @ NTU (ERI@N) Engineering::Materials Fluoropolyurethane Zinc Substrate A fluoropolyurethane-encapsulated process was designed to rapidly fabricate low-flow resistance surfaces on the zinc substrate. For the further enhancement of the drag-reduction effect, Cu2+-assisted chemical etching was introduced during the fabrication process, and its surface morphology, wettability, and flow-resistance properties in a microchannel were also studied. It is indicated that the zinc substrate with a micro-nanoscale roughness obtained by Cu2+-assisted nitric acid etching was superhydrophilic. However, after the etched zinc substrate is encapsulated with fluoropolyurethane, the superhydrophobic wettability can be obtained with a contact angle of 154.8° ± 2.5° and a rolling angle of less than 10°. As this newly fabricated surface was placed into a non-standard design microchannel, it was found that with the increase of Reynolds number, the drag-reduction rate of the superhydrophobic surface remained basically unchanged at 4.0% compared with the original zinc substrate. Furthermore, the prepared superhydrophobic surfaces exhibited outstanding reliability in most liquids. Ministry of Education (MOE) Published version This research was funded by MOE Academic Research Fund (AcRF) Tier 1 Project “Nano-structured Titania with tunable hydrophilic/hydrophobic behavior and photocatalytic function for marine structure application”, Grant Call (Call 1/2018) _MSE (EP Code EP5P, Project ID 122018-T1-001-077), Ministry of Education (MOE), Singapore. 2021-01-22T02:22:57Z 2021-01-22T02:22:57Z 2020 Journal Article Li, Y., Cui, Z., Zhu, Q., Narasimalu, S., & Dong, Z. (2020). Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching. Coatings, 10(4), 377-. doi:10.3390/coatings10040377 2079-6412 https://hdl.handle.net/10356/146050 10.3390/coatings10040377 2-s2.0-85083839146 4 10 377 en Coatings © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering::Materials
Fluoropolyurethane
Zinc Substrate
spellingShingle Engineering::Materials
Fluoropolyurethane
Zinc Substrate
Li, Yuanzhe
Cui, Zhe
Zhu, Qiucheng
Narasimalu, Srikanth
Dong, Zhili
Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
description A fluoropolyurethane-encapsulated process was designed to rapidly fabricate low-flow resistance surfaces on the zinc substrate. For the further enhancement of the drag-reduction effect, Cu2+-assisted chemical etching was introduced during the fabrication process, and its surface morphology, wettability, and flow-resistance properties in a microchannel were also studied. It is indicated that the zinc substrate with a micro-nanoscale roughness obtained by Cu2+-assisted nitric acid etching was superhydrophilic. However, after the etched zinc substrate is encapsulated with fluoropolyurethane, the superhydrophobic wettability can be obtained with a contact angle of 154.8° ± 2.5° and a rolling angle of less than 10°. As this newly fabricated surface was placed into a non-standard design microchannel, it was found that with the increase of Reynolds number, the drag-reduction rate of the superhydrophobic surface remained basically unchanged at 4.0% compared with the original zinc substrate. Furthermore, the prepared superhydrophobic surfaces exhibited outstanding reliability in most liquids.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Li, Yuanzhe
Cui, Zhe
Zhu, Qiucheng
Narasimalu, Srikanth
Dong, Zhili
format Article
author Li, Yuanzhe
Cui, Zhe
Zhu, Qiucheng
Narasimalu, Srikanth
Dong, Zhili
author_sort Li, Yuanzhe
title Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
title_short Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
title_full Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
title_fullStr Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
title_full_unstemmed Fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
title_sort fabrication of zinc substrate encapsulated by fluoropolyurethane and its drag-reduction enhancement by chemical etching
publishDate 2021
url https://hdl.handle.net/10356/146050
_version_ 1772828193696251904