A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene

• Main Authors: Rao, Bin, Kinjo, Rei
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2021
• 主題: Science::Chemistry; Boron; Germylenes
• 在線閱讀: https://hdl.handle.net/10356/146214

A cyclic (alkyl)(amino)germylene undergoes a ring expansion reaction with dibromomesitylborane (MesBBr2 ) to afford a six-membered dibromogermane derivative. In the presence of Lewis bases (PMe3 or Me NHC), reduction of the latter with two equivalents of potassium graphite (KC8 ) gives rise to cycli...