Borane-catalyzed cross-metathesis strategy for facile transformation of cyclic (alkyl)(amino)germylenes

A borane B(C6 F5 )3 -catalyzed metathesis reaction between the Si-C bond in the cyclic (alkyl)(amino)germylene (CAAGe) 1 and the Si-H bond in a silane (R3 SiH; 2) is reported. Mechanistic studies propose that the initial step of the reaction involves Si-H bond activation to furnish an ionic species...

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Bibliographic Details
Main Authors: Rao, Bin, Wang, Liliang, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/146199
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Institution: Nanyang Technological University
Language: English