Borane-catalyzed cross-metathesis strategy for facile transformation of cyclic (alkyl)(amino)germylenes
A borane B(C6 F5 )3 -catalyzed metathesis reaction between the Si-C bond in the cyclic (alkyl)(amino)germylene (CAAGe) 1 and the Si-H bond in a silane (R3 SiH; 2) is reported. Mechanistic studies propose that the initial step of the reaction involves Si-H bond activation to furnish an ionic species...
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Main Authors: | Rao, Bin, Wang, Liliang, Kinjo, Rei |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2021
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/146199 |
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Institution: | Nanyang Technological University |
Language: | English |
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