1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid

• المؤلفون الرئيسيون: Loh, Ying Kai, Chong, Che Chang, Ganguly, Rakesh, Li, Yongxin, Vidovic, Dragoslav, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2016
• الموضوعات: borane derivative; ab initio calculation
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/81976; http://hdl.handle.net/10220/41051
• المؤسسة: Nanyang Technological University

The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property.