Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalent

An autoionization of germanium dichloride/dioxane complex with an imino-N-heterocyclic carbene ligand (L) afforded a novel germyliumylidene ion, [(L)GeCl]+[GeCl3]−, which was fully characterized. Reduction of the germyliumylidene ion with potassium graphite produced a cyclic species [(L)Ge], which c...

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Bibliographic Details
Main Authors: Su, Bochao, Ganguly, Rakesh, Li, Yongxin, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/103941
http://hdl.handle.net/10220/24633
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Institution: Nanyang Technological University
Language: English