Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile

An isolable phenylborylene species supported by two oxazol-2-ylidene ligands was synthesized and structurally characterized. Computational studies revealed the presence of lone-pair electrons on the boron atom in this molecule; therefore, there are eight electrons around the three-coordinate boron c...

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Bibliographic Details
Main Authors: Vidović, Dragoslav, Kong, Ling Bing, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/105355
http://hdl.handle.net/10220/20493
http://dx.doi.org/10.1002/anie.201405201
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Institution: Nanyang Technological University
Language: English