Radiation-induced preparation of metal nanostructures in coatings of interpolyelectrolyte complexes

Radiation-induced preparation of metal nanostructures in coatings of interpolyelectrolyte complexes

Copper, silver and gold nanoparticles were obtained by reduction of metal ions under X-ray irradiation of “layer-by-layer” (LbL) coatings in a water-alcohol medium. The precursors for metal polymer composites (metallopolymer complexes) were prepared by sorption of metal ions in polyethyleneimine - p...

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Bibliographic Details
Main Authors: Klimov, Dmitry I., Zezina, Elena A., Lipik, Vitali, Abramchuk, Sergey S., Yaroslavov, Alexander A., Feldman, Vladimir I., Sybachin, Andrey V., Spiridonov, Vasily V., Zezin, Alexey A.
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2021
Subjects:
Engineering::Materials
X-ray Irradiation
Copper Silver Gold Nanoparticles
Online Access:https://hdl.handle.net/10356/147134
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Institution: Nanyang Technological University
Language: English
Description
Summary:Copper, silver and gold nanoparticles were obtained by reduction of metal ions under X-ray irradiation of “layer-by-layer” (LbL) coatings in a water-alcohol medium. The precursors for metal polymer composites (metallopolymer complexes) were prepared by sorption of metal ions in polyethyleneimine - poly (styrenesulfonic acid) and polyethyleneimine - poly (acrylic acid) coatings deposited on cotton fibers. EPR spectroscopy was use to characterize the complexation of metal ions in coatings with different chemical structure and variable number of polyanion-polycation layers. The effect of coating structure and thickness on the size and stability of nanoparticles was studied using TEM and microdiffraction measurements. Antibacterial activity was found for composites containing silver nanoparticles.

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