The interplay between the suprafacial and intrafacial mechanisms for complete methane oxidation on substituted LaCoO3 perovskite oxides

• Main Authors: Wang, Ting, Zhang, Chao, Wang, Jieyu, Li, Haiyan, Duan, Yan, Liu, Zheng, Lee, Jun Yan, Hu, Xiao, Xi, Shibo, Du, Yonghua, Sun, Shengnan, Liu, Xianhu, Lee, Jong-Min, Wang, Chuan, Xu, Zhichuan Jason
• Other Authors: School of Materials Science and Engineering
• Format: Article
• Language: English
• Published: 2021
• Subjects: Science::Chemistry::Physical chemistry::Catalysis; Methane Complete Oxidation; Mechanistic Pathways
• Online Access: https://hdl.handle.net/10356/148438
• Institution: Nanyang Technological University

The rational design of efficient catalysts can be guided by identifying proper descriptors that can rationalize and predict the catalytic behaviors. This study presents the feasibility of using the relative position between O p-band center and B-site metal cation d-band center as an activity descrip...