Silver(I)-selective electrodes based on rare earth element double-decker porphyrins

Silver(I)-selective electrodes based on rare earth element double-decker porphyrins

Various double-decker porphyrins accommodating rare earth elements (Sm, Tb, Y) were investigated as ionophores in potentiometric ion sensors. The studied ion-selective electrodes based on double-decker porphyrins were primarily selective to Ag ions. The experimentally derived selectivity coefficien...

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Bibliographic Details
Main Authors: Joon, Narender Kumar, Barnsley, Jonathan E., Ding, Ruiyu, Lee, Sunri, Latonen, Rose-Marie, Bobacka, Johan, Gordon, Keith C., Ogawa, Takuji, Lisak, Grzegorz
Other Authors: School of Civil and Environmental Engineering
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Ion-selective Electrode
Double-decker Porphyrins
Online Access:https://hdl.handle.net/10356/149254
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Institution: Nanyang Technological University
Language: English
Description
Summary:Various double-decker porphyrins accommodating rare earth elements (Sm, Tb, Y) were investigated as ionophores in potentiometric ion sensors. The studied ion-selective electrodes based on double-decker porphyrins were primarily selective to Ag ions. The experimentally derived selectivity coefficients were compared to theoretical predictions based on density functional theory (DFT) calculations of the metal-binding energies (ΔE) of double-decker porphyrin-metal ion complexes. Although DFT calculations were performed in vacuo, without taking into account ion-solvent and ion-membrane interactions, this computational approach showed relatively good correlation with the experimentally observed selectivity patterns of the ion-selective electrodes. Thus, DFT calculations were found to be a useful predictive tool when designing new ionophores for ion-selective electrodes.

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