A double-layer mechanochromic hydrogel with multidirectional force sensing and encryption capability

Hydrogel-based soft mechanochromic materials that display colorimetric changes upon mechanical stimuli have attracted wide interest in sensors and display device applications. A common strategy to produce mechanochromic hydrogels is through photonic structures, in which mechanochromism is obtained b...

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Main Authors: Zhu, Qingdi, Van Vliet, Krystyn, Holten-Andersen, Niels, Miserez, Ali
其他作者: School of Materials Science and Engineering
格式: Article
語言:English
出版: 2021
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在線閱讀:https://hdl.handle.net/10356/150195
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機構: Nanyang Technological University
語言: English
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總結:Hydrogel-based soft mechanochromic materials that display colorimetric changes upon mechanical stimuli have attracted wide interest in sensors and display device applications. A common strategy to produce mechanochromic hydrogels is through photonic structures, in which mechanochromism is obtained by strain-dependent diffraction of light. Here, a distinct concept and simple fabrication strategy is presented to produce luminescent mechanochromic hydrogels based on a double-layer design. The two layers contain different luminescent species—carbon dots and lanthanide ions—with overlapped excitation spectra and distinct emission spectra. The mechanochromism is rendered by strain-dependent transmittance of the top-layer, which regulates light emission from the bottom-layer to control the overall hydrogel luminescence. An analytical model is developed to predict the initial luminescence color and color changes as a function of uniaxial strain. Finally, this study demonstrates proof-of-concept applications of the mechanochromic hydrogel for pressure and contact force sensors as well as for encryption devices.