Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes

A simple catalyst-free and solvent-free method for the cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of various aldehydes with malononitrile was developed. The developed protocol demonstrated high efficiency in the two C–C bond...

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Main Authors: Wang, Weifan, Luo, Man, Yao, Weiwei, Ma, Mengtao, Pullarkat, Sumod A., Xu, Li, Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
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Online Access:https://hdl.handle.net/10356/150301
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1503012021-06-04T06:17:13Z Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes Wang, Weifan Luo, Man Yao, Weiwei Ma, Mengtao Pullarkat, Sumod A. Xu, Li Leung, Pak-Hing School of Physical and Mathematical Sciences Engineering::Chemical engineering Catalyst-free Solvent-free A simple catalyst-free and solvent-free method for the cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of various aldehydes with malononitrile was developed. The developed protocol demonstrated high efficiency in the two C–C bond formation scenarios. 2021-06-04T06:17:12Z 2021-06-04T06:17:12Z 2019 Journal Article Wang, W., Luo, M., Yao, W., Ma, M., Pullarkat, S. A., Xu, L. & Leung, P. (2019). Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes. ACS Sustainable Chemistry and Engineering, 7(1), 1718-1722. https://dx.doi.org/10.1021/acssuschemeng.8b05486 2168-0485 0000-0001-9629-6464 0000-0002-4150-2408 0000-0003-3588-1664 https://hdl.handle.net/10356/150301 10.1021/acssuschemeng.8b05486 2-s2.0-85058633655 1 7 1718 1722 en ACS Sustainable Chemistry and Engineering © 2018 American Chemical Society. All rights reserved.
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering::Chemical engineering
Catalyst-free
Solvent-free
spellingShingle Engineering::Chemical engineering
Catalyst-free
Solvent-free
Wang, Weifan
Luo, Man
Yao, Weiwei
Ma, Mengtao
Pullarkat, Sumod A.
Xu, Li
Leung, Pak-Hing
Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
description A simple catalyst-free and solvent-free method for the cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of various aldehydes with malononitrile was developed. The developed protocol demonstrated high efficiency in the two C–C bond formation scenarios.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Weifan
Luo, Man
Yao, Weiwei
Ma, Mengtao
Pullarkat, Sumod A.
Xu, Li
Leung, Pak-Hing
format Article
author Wang, Weifan
Luo, Man
Yao, Weiwei
Ma, Mengtao
Pullarkat, Sumod A.
Xu, Li
Leung, Pak-Hing
author_sort Wang, Weifan
title Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
title_short Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
title_full Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
title_fullStr Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
title_full_unstemmed Catalyst-free and solvent-free cyanosilylation and Knoevenagel condensation of aldehydes
title_sort catalyst-free and solvent-free cyanosilylation and knoevenagel condensation of aldehydes
publishDate 2021
url https://hdl.handle.net/10356/150301
_version_ 1702431265812119552