A general approach to non-fullerene electron acceptors based on the corannulene motif
Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C₆₀, and the prevalent fullerene-based elec...
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sg-ntu-dr.10356-1503122021-06-11T02:09:39Z A general approach to non-fullerene electron acceptors based on the corannulene motif Barát, Viktor Budanović, Maja Halilovic, Dzeneta Huh, June Webster, Richard David Mahadevegowda, Surendra Hittanahalli Stuparu, Mihaiela Corina School of Physical and Mathematical Sciences School of Materials Science and Engineering Science::Chemistry Corannulene Fullerene Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C₆₀, and the prevalent fullerene-based electron acceptor phenyl-C₆₁-butyric acid methyl ester (PCBM). Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University Support from the MoE under the AcRF Tier 1 (M4011792) (M4012047); A*STAR AME IRG A1883c0006; and NTU (M4081566) is gratefully acknowledged. J. H. thanks Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (2018M3D1A1058536). 2021-06-11T02:09:39Z 2021-06-11T02:09:39Z 2019 Journal Article Barát, V., Budanović, M., Halilovic, D., Huh, J., Webster, R. D., Mahadevegowda, S. H. & Stuparu, M. C. (2019). A general approach to non-fullerene electron acceptors based on the corannulene motif. Chemical Communications, 55(21), 3113-3116. https://dx.doi.org/10.1039/C9CC00327D 1359-7345 https://hdl.handle.net/10356/150312 10.1039/C9CC00327D 21 55 3113 3116 en M4011792 M4012047 A1883c0006 M4081566 Chemical Communications © 2019 The Royal Society of Chemistry. All rights reserved. |
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Nanyang Technological University |
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English |
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Science::Chemistry Corannulene Fullerene |
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Science::Chemistry Corannulene Fullerene Barát, Viktor Budanović, Maja Halilovic, Dzeneta Huh, June Webster, Richard David Mahadevegowda, Surendra Hittanahalli Stuparu, Mihaiela Corina A general approach to non-fullerene electron acceptors based on the corannulene motif |
| description |
Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C₆₀, and the prevalent fullerene-based electron acceptor phenyl-C₆₁-butyric acid methyl ester (PCBM). |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Barát, Viktor Budanović, Maja Halilovic, Dzeneta Huh, June Webster, Richard David Mahadevegowda, Surendra Hittanahalli Stuparu, Mihaiela Corina |
| format |
Article |
| author |
Barát, Viktor Budanović, Maja Halilovic, Dzeneta Huh, June Webster, Richard David Mahadevegowda, Surendra Hittanahalli Stuparu, Mihaiela Corina |
| author_sort |
Barát, Viktor |
| title |
A general approach to non-fullerene electron acceptors based on the corannulene motif |
| title_short |
A general approach to non-fullerene electron acceptors based on the corannulene motif |
| title_full |
A general approach to non-fullerene electron acceptors based on the corannulene motif |
| title_fullStr |
A general approach to non-fullerene electron acceptors based on the corannulene motif |
| title_full_unstemmed |
A general approach to non-fullerene electron acceptors based on the corannulene motif |
| title_sort |
general approach to non-fullerene electron acceptors based on the corannulene motif |
| publishDate |
2021 |
| url |
https://hdl.handle.net/10356/150312 |
| _version_ |
1702431154260410368 |