Investigating palladium pincer complexes in catalytic asymmetric hydrophosphination and hydroarsination

• المؤلفون الرئيسيون: Tay, Wee Shan, Yang, Xiang-Yuan, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry; Cross-coupling Reactions; Enantioselective Hydrophosphination
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/150654
• المؤسسة: Nanyang Technological University

Given the periodic relationship of phosphines and arsines, is remodeling the catalytic asymmetric hydrophosphination reaction an efficient manner to develop the corresponding hydroarsination reaction? Herein, a chiral PCP-Pd(II) pincer complex adept at generating enantioenriched phosphines was exami...