Access to C-Stereogenic PN(sp²)P Pincer Ligands via Phosphapalladacycle Catalyzed Asymmetric Hydrophosphination

A series of PN(sp2)P ligands containing two stereogenic carbon centers were generated via the palladium(II) catalyzed asymmetric hydrophosphination of 2,6-pyridyl dienones using diphenylphosphine. Although the targeted tridentate products are powerful metal ion sequesters, poisoning of the metal cat...

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Bibliographic Details
Main Authors: Foo, Ce Qing, Sadeer, Abdul, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/160148
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Institution: Nanyang Technological University
Language: English