Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral phosphines

A chiral palladacycle-promoted enantioselective asymmetric hydrophosphination of substituted methylidenemalonate esters using diphenylphosphine that provides direct access to chiral tertiary phosphines is reported. Screening of three easily accessible C,N and C,P palladacycles as catalysts for this...

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Bibliographic Details
Main Authors: Pullarkat, Sumod A., Xu, Chang, Gan, Kennard Jun Hao, Hennersdorf, Felix, Li, Yongxin, Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/101494
http://hdl.handle.net/10220/13698
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Institution: Nanyang Technological University
Language: English